You might want to try a couple of things, one would be to mix things up a bit, invite them over, get her off her turf. Take the high road and don't ignore her inappropriate behavior but change your response. When she asks those none-of-her-business questions, give her a blank look and in a completely flat voice ask, "why would you want to know?" Other responses you can use are: "Oh,(pause) really?", "Why would you say that?", "I don't consider that any of My business" or just very pointedly and meaninlessly change the subject, "Do you think that quantum theory has any application on a macro level?" "Oh did you get new throw pillows?"
Since she like to be the focus you could try, when she starts in, looking at her quizically and saying ,"There's something different about you. I can't quite put my finger on it." If she suggests something like her hair style, look doubtful and say, " well maybe". Then whenever she needs redirecting pull it back up, "I don't think it is your hair..."
Just keep her off guard.
Your husband sounds like a nice guy but maybe a bit nieve about women or at least certain types of women. Don't push it too hard, it's better to have him knowing he can be honest with you. Can you turn this into a joke? The ex sees how happy you are, she wants in on the action? He's perfect for you, not her.
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